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Lunar bulk chemical composition: a post-Gravity Recovery and Interior Laboratory reassessment

机译:月球散装化学成分:重力恢复和室内实验室后的重新评估

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摘要

New estimates of the thickness of the lunar highlands crust based on data from the Gravity Recovery and Interior Laboratory mission, allow us to reassess the abundances of refractory elements in the Moon. Previous estimates of the Moon fall into two distinct groups: earthlike and a 50% enrichment in the Moon compared with the Earth. Revised crustal thicknesses and compositional information from remote sensing and lunar samples indicate that the crust contributes 1.13–1.85 wt% Al2O3 to the bulk Moon abundance. Mare basalt Al2O3 concentrations (8–10 wt%) and Al2O3 partitioning behaviour between melt and pyroxene during partial melting indicate mantle Al2O3 concentration in the range 1.3–3.1 wt%, depending on the relative amounts of pyroxene and olivine. Using crustal and mantle mass fractions, we show that that the Moon and the Earth most likely have the same (within 20%) concentrations of refractory elements. This allows us to use correlations between pairs of refractory and volatile elements to confirm that lunar abundances of moderately volatile elements such as K, Rb and Cs are depleted by 75% in the Moon compared with the Earth and that highly volatile elements, such as Tl and Cd, are depleted by 99%. The earthlike refractory abundances and depleted volatile abundances are strong constraints on lunar formation processes.
机译:根据重力恢复和内部实验室任务的数据,对月球高地壳厚度的新估计使我们能够重新评估月球中难熔元素的含量。先前对月球的估计分为两个不同的组:类土和月球与地球相比富集了50%。修改后的地壳厚度和来自遥感和月球样品的成分信息表明,地壳对月球体丰度的贡献为1.13–1.85%wt%Al2O3。母岩玄武岩中Al2O3的浓度(8-10%wt%)以及部分熔融过程中Al2O3在熔体和辉石之间的分配行为表明Al2O3的浓度在1.3-3.1%wt%范围内,具体取决于辉石和橄榄石的相对含量。使用地壳和地幔的质量分数,我们表明,月亮和地球最有可能具有相同(20%以内)的耐火元素浓度。这使我们能够使用成对的难熔性元素和挥发性元素之间的相关性,以确认与地球相比,月球中的K,Rb和Cs等中等挥发性元素的月度丰度比地球以及Tl等高挥发性元素的月度丰度降低了和Cd消耗了99%。土状耐火物的丰度和挥发物的耗尽是对月球形成过程的强烈制约。

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