Chlorido{N 2N 6-dibenzyl-N 2N 6-bis­(diphenyl­phosphan­yl)meth­ylpyridine-26-diamine}­methyl­platinum(II)

摘要

In the title mononuclear complex, [Pt(CH3)Cl(C45H41N3P2)], the pyridine-2,6-diamine ligand can be viewed as a centrosymmetric motif having two pendant N-benzyl-N-[(diphenyl­phosphan­yl)meth­yl] arms, the two P atoms of which chelate to the Pt^II ion, forming a ten-membered metallocycle. A distorted square-planar coordination geometry around the Pt^II atom is completed by a methyl ligand and a chloride ion. The packing between the mononuclear units is achieved through C—H⋯π inter­actions, which link the mol­ecules into chains along the c axis.