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Data on energy consumption in the production of layered double hydroxides

机译:层状双氢氧化物生产中的能耗数据

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摘要

Electrocoagulation consists of the in-situ generation of the coagulant by the electro dissolution of sacrificial electrodes (Mg and Al). This technique, besides being normally used for water treatment, can be used to synthesize Layered Double Hydroxides (LDH) or Hydrotalcites (HT) such as green rust, MgAlCl/LDH, and other oxides as Magnetite. The HT has a high tendency for water in the interlayer to be replaced by anions, these exchange characteristics generate a high interest in the fields of drug administration, photodegradation, catalyst supports, supercapacitors, and water oxidation. There are several routes of synthesis for these compounds such as co-precipitation, hydrolysis of urea, hydrothermal treatment and a novel route by electrocoagulation (EC).This work discloses the data of the energy consumption at laboratory-scale production in the synthesis of hydrotalcite (HT) or Layered Double Hydroxides (LDH) by electrocoagulation, the values obtained through these experiments are intended to provide support due to the lack of information on the energy consumption of this novel production method. Aluminum and AZ31 electrodes were used as a cations source during two- and four-hours operation, at 50 °C with 5 mA cm−2 of current density, and 5 minutes of polarity change for Aluminum and 8 minutes for AZ31 (Magnesium alloy).
机译:电凝包括通过牺牲电极(Mg和Al)的电溶解原位产生凝结剂。除通常用于水处理外,该技术还可用于合成层状双氢氧化物(LDH)或水滑石(HT),例如生铁锈,MgAlCl / LDH和其他氧化物(如磁铁矿)。 HT具有较高的趋势,使中间层中的水被阴离子取代,这些交换特性引起了药物管理,光降解,催化剂载体,超级电容器和水氧化等领域的高度关注。这些化合物的合成途径有多种,例如共沉淀,尿素水解,水热处理和电凝(EC)的新途径。这项工作公开了水滑石合成中实验室规模生产的能耗数据。电凝法(HT)或层状双氢氧化物(LDH),由于缺乏有关这种新型生产方法的能耗信息,因此通过这些实验获得的值旨在提供支持。铝和AZ31电极在50°C下,在5 mA·cm −2 的电流密度,50°C的温度下运行两小时和四小时的过程中用作阳离子源,铝和8电极的极性变化为5分钟AZ31(镁合金)的分钟。

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