Morphologic and chemical composition of particulate matter in motorcycle engine exhaust

摘要

class="kwd-title">Abbreviations: PAHs, polycyclic aromatic hydrocarbons; ICE, internal combustion engines; EDTA, ethylenediaminetetraacetic acid; EFI, electronic fuel injection system; PM, particulate matter; PM10, particles with a diameter between 2,5 and 10 μm; VEPs, vehicle emitted particles; VOCs, volatile organic compounds class="kwd-title">Keywords: Polycyclic aromatic hydrocarbons, Particle size distribution, Chemical composition, Motorcycle exhaust gases, Environmental toxicology class="head no_bottom_margin" id="abs0015title">AbstractDespite the fact that environmental pollution due to motorcycle exhaust gases reports a great increase, motorcycle production exhibits a great increase through the last years. Countries of Asia and Africa are reported to be the major regions where two-wheeled vehicles are a major transportation mode, with tens of millions of units sold per year. Motorcycle exhaust particles are considered to be the major contributor to environmental pollution due to their airborne dispersion, containing great amount of polycyclic aromatic hydrocarbons (PAHs). This study aims at reporting an objective analysis of the main sources of the ambient air pollution as also particle size distribution and chemical composition analysis of particulate matter originated from the exhausts of two-wheeled vehicles used in the territory of Vladivostok, Russia. Various types of two-wheeled vehicles were examined (motorcycles, ATVs, scooters and wet bikes) using different types of engine and fuel system. Experimental results showed that there was no clear relation to the particle size distribution with the engine displacement of motorcycle and the number of strokes and the fuel system. Instead, there were reported two clear assumptions. The first one is that regarding to the motorcycle brand, a few samples did not exhibit a great percentage of PM10 fraction. The second one is that more modern vehicles, that have a harmful gas afterburning system, are usually the source of an increased percentage of PM10 emitted particles. At last, it should be mentioned that the laser particle size analysis method is capable of determining the particle sizes after their agglomeration whereas the optical morphometry method allows to determine the real particle size of emissions. In conclusion, it can be pointed out that the agglomeration of particles can lead to the reduction in the toxicity of particles emissions originated from two wheeled-vehicles.