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A Photoluminescence-Based Field Method for Detection of Traces of Explosives

机译:基于光致发光的炸药痕量场法

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摘要

We report a photoluminescence-based field method for detecting traces of explosives. In its standard version, the method utilizes a commercially available color spot test kit for treating explosive traces on filter paper after swabbing. The colored products are fluorescent under illumination with a laser that operates on three C-size flashlight batteries and delivers light at 532 nm. In the fluorescence detection mode, by visual inspection, the typical sensitivity gain is a factor of 100. The method is applicable to a wide variety of explosives. In its time-resolved version, intended for in situ work, explosives are tagged with europium complexes. Instrumentation-wise, the time-resolved detection, again visual, can be accomplished in facile fashion. The europium luminescence excitation utilizes a laser operating at 355 nm. We demonstrate the feasibility of CdSe quantum dot sensitization of europium luminescence for time-resolved purposes. This would allow the use of the above 532 nm laser.
机译:我们报告了一种基于光致发光的现场方法来检测炸药的痕迹。在其标准版本中,该方法利用可商购获得的色斑测试套件来处理擦拭后滤纸上的爆炸痕迹。有色产品在激光照射下发荧光,该激光在三个C尺寸手电筒电池上工作并发出532 nm的光。在荧光检测模式下,通过目视检查,典型的灵敏度增益为100倍。该方法适用于多种爆炸物。在用于现场工作的时间分辨版本中,炸药上标有tagged配合物。就仪器而言,时间分辨的检测,又是视觉上的,可以方便地完成。 excitation发光激发利用在355 nm下工作的激光。我们证明了for发光的CdSe量子点敏化用于时间分辨目的的可行性。这将允许使用上述532 nm激光器。

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