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Akaganeite nanorices deposited muscovite mica surfaces as sunlight active green photocatalyst

机译:赤铁矿纳米粒子沉积白云母云母表面作为日光活性绿色光催化剂

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摘要

Thin films of akaganeite [FeO(OH)] nanorices deposited muscovite mica (ANPM) surfaces are synthesized using the facile urea assisted controlled self-assembly technique. The synthesized materials are characterized using scanning electron microscopy (SEM) with energy-dispersive X-ray spectroscopy, atomic force microscopy, X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy and thermogravimetric analysis (TGA). The prepared nanorices on mica surfaces show average particle length and width of 200 and 50 nm, respectively. Synthesized material acts as an efficient photocatalyst under UV and sunlight conditions as demonstrated by the degradation of standard methylene blue (MB) solution. The MB degradation efficiencies of the catalyst under exposure to 180 min sunlight and UV are 89% and 87.5%, respectively, which shows that the catalyst is more highly active under sunlight than under UV light. Therefore, the synthesized material is a potential green photocatalyst in efficient treatment of industrial dye effluents under direct sunlight.
机译:使用方便的尿素辅助控制的自组装技术合成了赤铁矿[FeO(OH)]纳米颗粒沉积的白云母云母(ANPM)表面的薄膜。使用具有能量色散X射线光谱的扫描电子显微镜(SEM),原子力显微镜,X射线衍射(XRD),傅里叶变换红外(FT-IR)光谱和热重分析(TGA)对合成的材料进行表征。在云母表面上制备的纳米颗粒分别显示出200 nm和50 nm的平均颗粒长度和宽度。如标准亚甲基蓝(MB)溶液的降解所证明,合成的材料在紫外线和日光条件下可作为一种有效的光催化剂。暴露于180分钟的阳光和紫外线下,催化剂的MB降解效率分别为89%和87.5%,这表明该催化剂在阳光下比在紫外线下具有更高的活性。因此,合成材料是在阳光直射下有效处理工业染料废水的潜在绿色光催化剂。

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