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Relationship between thermoelectric figure of merit and energy conversion efficiency

机译:热电性能与能量转换效率的关系

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摘要

The formula for maximum efficiency (ηmax) of heat conversion into electricity by a thermoelectric device in terms of the dimensionless figure of merit (ZT) has been widely used to assess the desirability of thermoelectric materials for devices. Unfortunately, the ηmax values vary greatly depending on how the average ZT values are used, raising questions about the applicability of ZT in the case of a large temperature difference between the hot and cold sides due to the neglect of the temperature dependences of the material properties that affect ZT. To avoid the complex numerical simulation that gives accurate efficiency, we have defined an engineering dimensionless figure of merit (ZT)eng and an engineering power factor (PF)eng as functions of the temperature difference between the cold and hot sides to predict reliably and accurately the practical conversion efficiency and output power, respectively, overcoming the reporting of unrealistic efficiency using average ZT values.
机译:根据无量纲品质因数(ZT)的热电设备将热转换为电的最大效率(ηmax)的公式已广泛用于评估设备用热电材料的可取性。不幸的是,ηmax值取决于平均ZT值的使用方式而变化很大,这引起了人们对ZT适用性的质疑,因为由于忽略了材料特性的温度依赖性,在热侧和冷侧之间的温差较大时影响ZT。为避免复杂的数值模拟提供准确的效率,我们定义了工程无量纲的品质因数(ZT)eng和工程功率因数(PF)eng作为冷端和热端之间的温差的函数,以可靠且准确地进行预测实际转换效率和输出功率分别克服了使用平均ZT值报告不现实效率的情况。

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