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Microflow Mechanism of Oil Displacement by Viscoelastic Hydrophobically Associating Water-Soluble Polymers in Enhanced Oil Recovery

机译:粘弹性疏水缔合水溶性聚合物驱油的微流机理提高采收率

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摘要

Polymer flooding plays an important role in enhanced oil recovery (EOR), particularly in China, where partially hydrolyzed polyacrylamide (HPAM) and hydrophobically associating water-soluble polymers (HAWP) are used in onshore and offshore reservoirs, respectively. Many researchers have highlighted the elasticity of HPAM, which can be used to improve the sweep efficiency, i.e., the ratio of the area swept by an injected fluid to the oil area. On the other hand, fewer studies exist on the elasticity of HAWP. In this study, we investigate the flow of HAWP and Xanthan solutions with identical viscosities in core experiments in terms of elasticity; results reveal that the HAWP can produce shear thickening in the core. The constitutive equation for the HAWP can be obtained using the simulation results matched with the experimental data. On the basis of these experiments, we established a two-phase flow model of a polymer and oil, including the continuity, momentum, constitutive, and phase equations. The volume-of-fluid (VOF) method was used to track the interface between the two phases. A complex pore model was established based on the glass-etched model used in the experiment. We used the OpenFOAM platform to solve the mathematical model. The saturation, pressure, and stress tensor distributions were obtained. The results show that the displacement efficiency increased as the elasticity of the polymer increased; accordingly, the elasticity can enlarge the sweep area and decrease the residual oil saturation. As the elasticity increases, the stresses (the first normal stress, second normal stress, and shear stress) increase. Finally, the results obtained in this study can be used as a guideline in polymer design, screening, and optimization in the polymer flooding oilfields.
机译:聚合物驱在提高石油采收率(EOR)中起着重要作用,特别是在中国,在陆上和海上储层分别使用部分水解的聚丙烯酰胺(HPAM)和疏水缔合水溶性聚合物(HAWP)。许多研究人员强调了HPAM的弹性,该弹性可用于提高扫掠效率,即注入流体扫过的面积与油层的比率。另一方面,关于HAWP弹性的研究较少。在这项研究中,我们在弹性实验中研究了粘度相同的HAWP和黄原胶溶液的流动性。结果表明,HAWP可以在岩心中产生剪切增稠作用。利用与实验数据相匹配的仿真结果,可以得到HAWP的本构方程。在这些实验的基础上,我们建立了聚合物和油的两相流模型,包括连续性,动量,本构和相方程。流体体积(VOF)方法用于跟踪两相之间的界面。基于实验中使用的玻璃蚀刻模型建立了复杂的孔模型。我们使用OpenFOAM平台求解数学模型。获得了饱和度,压力和应力张量分布。结果表明,随着聚合物弹性的增加,驱替效率也随之提高。因此,弹性可以扩大扫掠面积并降低残余油饱和度。随着弹性的增加,应力(第一法向应力,第二法向应力和剪切应力)增加。最后,本研究中获得的结果可以用作聚合物驱油田中聚合物设计,筛选和优化的指导。

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