Crystal structure of di-μ-chlorido-bis­(chlorido­{N1N1-diethyl-N4-(pyridin-2-yl-κN)methyl­idenebenzene-14-di­amine-κN4}mercury(II))

摘要

The title dinuclear mercury(II) complex, [Hg2Cl4(C16H19N3)2], synthesized from the pyridine-derived Schiff base (E)-N ¹,N ¹-diethyl-N ⁴-[(pyridin-2-yl)methyl­idene]benzene-1,4-di­amine (DPMBD), has inversion symmetry. The five-coordinated Hg^II atoms have distorted square-pyramidal stereochemistry comprising two N-atom donors from bidentate chelate BPMBD ligands and three Cl-atom donors, two bridging and one monodentate. The dihedral angle between the benzene and the pyridine rings in the BPMBD ligand is 7.55 (4)°. In the crystal, the dinuclear mol­ecules are linked by weak C—H⋯Cl hydrogen bonds, forming zigzag ribbons lying parallel to [001]. Also present in the structure are π–π inter­actions between benzene and pyridine rings [minimum ring-centroid separation = 3.698 (8) Å].