Sb2S3@PPy Coaxial Nanorods: A Versatile and Robust Host Material for Reversible Storage of Alkali Metal Ions

摘要

Chalcogenides have attracted great attention as functional materials in optics, electronics, and energy-related applications due to their typical semiconductor properties. Among those chalcogenides, Sb2S3 holds great promise in energy storage field, especially as an anode material for alkali metal (Li, Na, and K) batteries. In this work, a one-dimensional coaxial Sb2S3@PPy is investigated as a versatile and robust anode in three kinds of alkali metal batteries for the first time, and the energy storage mechanism of these batteries is systematically discussed. As an anode material for sodium ion batteries (SIBs) and potassium ion batteries (KIBs), Sb2S3@PPy exhibits high reversible capacity and impressive cycle lifespan. Sb2S3@PPy anode demonstrates an adsorption behavior that has a significant influence on its sodium storage behavior, providing a universal model for studying the application of chalcogenide compounds.