【2h】

Additives in fibers and fabrics.

机译:纤维和织物中的添加剂。

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摘要

The additives and contaminants which occur in textile fibers vary widely, depending on the type of fiber and the pretreatment which it has received. Synthetic fibers such as nylon and polyester contain trace amounts of contaminants such as catalysts and catalyst deactivators which remain after the synthesis of the basic polymers. In addition, there are frequently a number of materials which are added to perform specific functions in almost all man-made fibers. Examples of these would include traces of metals or metal salts used as tracers for identification of specific lots of fiber, TiO2 or similar materials added as delustrants, and a host of organic species added for such special purposes as antistatic agents or flame retardants. There may also be considerable quantities of residual monomer or small oligomers dissolved in the polymer matrix. The situation becomes even more complex after the fibers are converted into fabric form. Numerous materials are applied at various stages of fabric preparation to act as lubricants, sizing agents, antistats, bleaches, and wetting agents to facilitate the processing, but these are normally removed before the fabric reaches the cutters of the ultimate consumers and therefore usually do not constitute potential hazards. However, there are many other chemical agents which are frequently added during the later stages of fabric preparation and which are not designed to be removed. Aside from dyes and printing pigments, the most common additive for apparel fabrics is a durable press treatment. This generally involves the use of materials capable of crosslinking cellulosics by reacting through such functions as N-methylolated amides or related compounds such as ureas and carbamates. These materials pose some potential hazards due to both the nitrogenous bases and the formaldehyde which they usually release. There is usually also some residual catalyst in fabrics which have received such treatments. Other types of chemical treatments which are often applied to fabrics to achieve special effects include flame retardants, soil release agents, antistatic agents, softeners, water and/or oil repellents, ultraviolet absorbers, bacteriostats, and fungistats.
机译:出现在纺织纤维中的添加剂和污染物变化很大,这取决于纤维的类型及其接受的预处理。诸如尼龙和聚酯的合成纤维含有痕量的污染物,例如催化剂和催化剂减活剂,这些污染物在碱性聚合物合成后仍然存在。另外,经常添加许多材料以在几乎所有人造纤维中执行特定功能。这些实例包括痕量的金属或金属盐,这些金属或金属盐被用作示踪剂,以识别特定批次的纤维,TiO2或添加为消臭剂的类似材料;以及为特殊目的而添加的多种有机物,例如抗静电剂或阻燃剂。聚合物基质中还可能溶解有相当数量的残留单体或小的低聚物。在纤维转变成织物形式之后,情况变得更加复杂。许多材料在织物制备的各个阶段被用作润滑剂,上浆剂,抗静电剂,漂白剂和湿润剂,以促进加工,但通常在织物到达最终消费者的切割机之前将其除去,因此通常不会构成潜在的危害。但是,还有许多其他化学试剂在织物制备的后期阶段经常添加,并且不能去除。除染料和印刷颜料外,服装面料最常见的添加剂是耐久压榨处理。这通常涉及使用能够通过诸如N-羟甲基化酰胺或相关化合物(如尿素和氨基甲酸酯)之类的功能反应而能够交联纤维素的材料。这些材料由于它们通常释放出的氮碱和甲醛而造成一些潜在的危害。经过这种处理的织物中通常还会残留一些催化剂。通常用于织物以达到特殊效果的其他类型的化学处理方法包括阻燃剂,去污剂,抗静电剂,柔软剂,拒水拒油剂,紫外线吸收剂,抑菌剂和抑菌剂。

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