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A New Carbon-Negative Precipitated Calcium Carbonate Admixture (PCC-A) for Low Carbon Portland Cements

机译:用于低碳硅酸盐水泥的新型碳负沉淀碳酸钙混合物(PCC-A)

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摘要

The production of Portland cement accounts for approximately 7% of global anthropogenic CO2 emissions. Carbon CAPture and CONversion (CAPCON) technology under development by the authors allows for new methods to be developed to offset these emissions. Carbon-negative Precipitated Calcium Carbonate (PCC), produced from CO2 emissions, can be used as a means of offsetting the carbon footprint of cement production while potentially providing benefits to cement hydration, workability, durability and strength. In this paper, we present preliminary test results obtained for the mechanical and chemical properties of a new class of PCC blended Portland cements. These initial findings have shown that these cements behave differently from commonly used Portland cement and Portland limestone cement, which have been well documented to improve workability and the rate of hydration. The strength of blended Portland cements incorporating carbon-negative PCC Admixture (PCC-A) has been found to exceed that of the reference baseline—Ordinary Portland Cement (OPC). The reduction of the cement clinker factor, when using carbon-negative PCC-A, and the observed increase in compressive strength and the associated reduction in member size can reduce the carbon footprint of blended Portland cements by more than 25%.
机译:波特兰水泥的产量约占全球人为二氧化碳排放量的7%。作者正在开发的碳捕获和转化(CAPCON)技术允许开发新的方法来抵消这些排放。由二氧化碳排放产生的碳负沉淀碳酸钙(PCC)可以用作抵消水泥生产中碳足迹的一种手段,同时可能为水泥的水化,可加工性,耐久性和强度带来好处。在本文中,我们介绍了新型PCC掺合波特兰水泥的力学和化学性能的初步测试结果。这些初步发现表明,这些水泥的性能与常用的波特兰水泥和波特兰石灰石水泥不同,这些文献已被证明可以改善可使用性和水合速率。已发现掺入碳负PCC掺合料(PCC-A)的波特兰水泥的强度超过了基准基线-普通波特兰水泥(OPC)的强度。当使用负碳PCC-A时,降低水泥熟料系数,并观察到抗压强度的提高和相关的构件尺寸的减小,可使混合波特兰水泥的碳足迹降低25%以上。

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