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Smelting of Scandium by Microwave Irradiation

机译:微波辐照Scan的冶炼

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摘要

Scandium is being explored as an alloying element for aluminum alloys, which are gaining importance as high-performance lightweight structural alloys in the transportation industry. A few years ago, Sc was also found to be suitable for use in electrical devices. High-Sc-content ScAlN thin films have attracted significant attention because of their strong piezoelectricity. The piezoelectric response of ScAlN suggests that ScAlN thin films formed on a hard substrate would be suitable surface acoustic wave wideband filters for next-generation wireless communication systems. However, it is often difficult to use ScAlN thin films in MEMS devices—including acoustic ones—because of the extremely high price of metallic Sc, given the difficulty associated with smelting it. Here, we propose a novel process for smelting Sc metal by microwave irradiation. Sc metal was able to be obtained successfully from ScF3 through a microwave-irradiation-based carbon reduction reaction. The reaction temperature for this reduction process was approximately 880°C, which is half of that for the conventional smelting process involving reduction with Ca. Thus, the proposed microwave irradiation process has significant potential for use in the smelting of Sc metal.
机译:dium被探索为铝合金的合金元素,在交通行业中,as作为高性能轻质结构合金正变得越来越重要。几年前,还发现Sc适用于电子设备。高Sc含量的ScAlN薄膜由于其强大的压电性而引起了广泛的关注。 ScAlN的压电响应表明,在硬质基底上形成的ScAlN薄膜将是下一代无线通信系统的合适表面声波宽带滤波器。但是,由于金属Sc的冶炼难度很大,因此在MEMS器件(包括声学器件)中通常很难使用ScAlN薄膜,因为金属Sc的价格非常高。在这里,我们提出了一种通过微波辐射冶炼Sc金属的新工艺。通过基于微波照射的碳还原反应,可以从ScF3成功地获得Sc金属。该还原过程的反应温度约为880℃,是涉及用Ca还原的常规熔炼过程的反应温度的一半。因此,所提出的微波辐照工艺具有用于熔炼potential金属的巨大潜力。

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