Tuning of Catalytic Property Controlled by the MolecularDimension of Palladium–Schiff Base Complexes Encapsulated inZeolite Y

摘要

Planar palladium–Schiff base complexes are synthesized, maintaining the order of their molecular dimensions as PdL1 < PdL2 < PdL3 < PdL4 < PdL5 in free state, as well as encapsulated in zeolite Y, where L1: N,N′-bis(salicylidene)ethylenediamine and L2, L3, L4, and L5 are derivatives of L1. All encapsulated complexes have shown better catalytic activity for the sulfoxidation of methyl phenyl sulfide in comparison to their homogeneous counter parts. These hybrid systems are characterized with the help of different characterization techniques such as X-ray diffraction analysis, scanning electron microscopy–energy-dispersive X-ray spectrometry, X-ray photoelectron spectroscopy, Fourier transform infrared, and UV–visible spectroscopy; all of these studies have suggested that the largest complex deviates by the maximum from its free-state properties, and a radical change in the reactivity of the complex is observed.