Application of Corncob-Based Activated Carbon as Electrode Material for Electric Double-Layer Capacitors

摘要

To investigate the influence of expansion pretreatment for materials on carbon structure, activated carbons (ACs) were prepared from corncob with/without expansion pretreatment by KOH activation, the structure properties of which were determined based on N 2 adsorption isotherm at 77 K. The results show that the expansion pretreatment for corncobs is beneficial to the preparation of ACs with high surface area. The specific surface area of the AC derived from corncob with expansion pretreatment (AC-1) is 32.5% larger than that without expansion pretreatment (AC-2). Furthermore, to probe the potential application of corncob-based ACs in electric double-layer capacitor (EDLC), the prepared ACs were used as electrode materials to assemble EDLC, and its electrochemical performance was investi- gated. The results indicate that the specific capacitance of AC-1 is 276 F/g at 50 mA/g, which increases by 27% com- pared with that of AC-2 (217 F/g). As electrode materials, AC-1 presents a better electrochemical performance than AC-2, including a higher voltage maintenance ratio and a lower leakage current.