As a raw material,kaolin was modified to prepare a high-performance ammonium ion-exchange material.According to cation-exchange capacity (CEC) measurement,the prepared ammonium ion-exchange material has an ammonium ion-exchange capacity greater than 75mg/g and can be used to remove ammonia nitrogen in water treatment.A pharmaceutical extruder-rounder was used to study the effects of granulation process.Polyethylene glycol6000 (PEG-6000) was used as the pore-forming agent and calcining temperature of 650℃ was used as the optimal condition.NMR data indicate that 27 Al is mainly converted from hexa-coordinated Al to tetra-coordinated Al during the modification.Compared with 29 Si in the original kaolin,29 Si in the modified kaolin does not have an obvious change.A comparison of the data with Langmuir and Freundlich isotherm models shows a good correlation.The Freundlich model describes the process more accurately,and the adsorption process of ammonia nitrogen in water with the ammonium ion-exchange material closely matches the pseudo-second-order reaction.
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