<正>The electron structure ofγ/α2 phase boundaries in lamellar colonies in Ti-47Al-2M(M=Nb, Cr, V) (mole fraction, %) alloys was theoretically investigated by Empirical Electron Theory of Solid and Molecules (EET) and the bond-length-difference (BLD) method. Average-Atom-Model was employed to calculate valence electron structure of TiAl intermetallics containing site substitution elements. On this basis, the boundary condition of electron movement was employed in the improved Thomas-Fermi-Dirac (TFD) theory to decide the continuity of the electron density of the lamellar colonies interface and it is found that ofγ/α2 interface is continuous(Δρ<10%). Furthermore, it is found that adding alloying elements (including Nb, Cr, and V) can improve the electron density (ρ) ofγ/α2 interfaces, and decrease the electron density difference(Δρ)ofγ/α2 interfaces. Adding V element decreasingΔρis more remarkable than other site substitution elements. According to electron structure study ofγ/α2 interfaces in Ti-47Al-2M alloys, the added elements improve mechanical properties of the alloy in the following order: V>Cr>Nb.
展开▼