Effect of Y2O3 on microstructure and oxidation of γ-Ni+γ'-Ni3Al coatings transformed from electrodeposited Ni-Al films at 1 000 ℃

摘要

The electrodeposited Y2O3-dispersed γ-Ni+γ'-Ni3Al coatings on Ni substrates were developed by the conversion of electrodeposited Ni-Al-Y2O3 films with dispersed Al microparticles in Ni matrix into Ni3Al by vacuum annealing at 800 ℃ for 3 h. For comparison, Y2O3-free (γ-Ni+γ'-Ni3Al coatings with a similar Al content were also prepared by vacuum annealing the electrodeposited microparticle-dispersed composite coatings of Ni-Al under the same condition. SEM and TEM characterizations show that the electrodeposited Y2O3-dispersed γ+γ' coatings exhibit finer grains, a more homogeneous distribution of γ', and a narrowed γ' phase spacing compared with the electrodeposited Y2O3-free γ+γ' coatings. The oxidation at 1 000 ℃ shows that the addition of Y2O3 significantly improves the oxidation resistance of the electrodeposited γ+γ'coatings. The effect of Y2O3 particles on the microstructure and oxidation behavior of the electrodeposited γ+γ' coatings was discussed in detail.