Al-Cu-Li-Mn-Zr-Ti合金在均匀化过程中的组织演变

摘要

采用光学显微镜(OM)、扫描电镜(SEM)、能谱分析(EDX)和差示扫描热分析法(DSC)研究 Al−Cu−Li−Mn−Zr−Ti 合金在均匀化过程中的组织转变。结果表明，实验合金的铸态组织中存在严重的枝晶偏析，晶界处存在大量的共晶相，主要合金元素沿枝晶区域呈周期性分布。合金中的主要未溶相为Al2Cu相，过烧温度为520°C；均匀化过程中，随着温度的升高和时间的延长，晶界处的第二相逐渐溶入基体中，晶界逐渐变得稀疏；合金的均匀化过程可以用一指数方程描述；实验合金适宜的均匀化制度为(510°C，18 h)，这与采用均匀化动力学方程计算的结果基本吻合。%The microstructure evolution of Al−Cu−Li−Mn−Zr−Ti alloy during homogenization was investigated by optical microscopy (OM), scanning electron microscopy (SEM), energy dispersive X-ray spectrometry (EDX), and differential scanning calorimeter (DSC) methods. The results show that severe dendritic segregation exists in the experimental alloy ingot. Numerous eutectic phases can be observed in the grain boundary, and the distribution of the main elements along the interdendritic region varies periodically. The main secondary phase is Al2Cu. The overburnt temperature of the alloy is 520 °C. The second phases are gradually dissolved into the matrix, and the grain boundaries become spare and thin during homogenization with increasing temperature or prolonging holding time. Homogenization can be described by a constitutive equation in exponential function. The suitable homogenization treatment for the alloy is (510 °C, 18 h), which agrees well with the results of homogenization kinetic analysis.