Realizing a high luminescence dissymmetry factor(glum)is a paramount yet challenging issue in the research field of circularly polarized luminescence(CPL).Here,we reported a novel set of organic conjugated systems with twisted intramolecular charge transfer(TICT)characteristics based on conjugated o-carborane-binaphthyl dyads composing of binaphthyl units as chiral electron donors and o-carborane units as achiral electron acceptors,demonstrating intense CPL with large glum values.Interestingly,single-crystalline o-l exhibited a high-level brightness and a large glum factor as high as+0.13,whereas single-crystalline o-2 processed a relatively low brightness with a decreased glum value to-0.04.The significant diversity of CPL-active properties was triggered by the selective introduction of o-carborane units onto the binaphthyl units.Benefiting from the large magnetic dipole transition moments in TICT states,the CPL activity of TICT o-carborane-based materials exhibited amplified circular polarization.This study provides an efficient molecular engineering strategy for the rational design and development of highly efficient CPL-active materials.
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