Extraction and separation of Ga(Ⅲ) and T1(Ⅰ) or In(Ⅲ) and T1(Ⅰ) from chloride media with CA-12 in sulphonating kerosene

摘要

The extraction behavior and mechanism of gallium(Ⅲ) and thallium(Ⅰ) or indium(Ⅲ) and thallium(Ⅰ) with Sec-octylphenoxy acetic acid (CA-12) from hydrochloric acid solution in sulphonating kerosene were studied. Optimum extraction conditions were evaluated from critical study of various experimental parameters and the probable composition of the extracted species is ascertained from lg D-lg C plots. The effects of different ions on the determination of these ions were examined.