A strategy to achieve efficient green-emission dual-mode luminescence of Yb^(3+),Er^(3+) doped NaBiF_(4)

摘要

A series of hexagonal phase NaBiF_(4):x Yb^(3+),y Er^(3+) were successfully synthesized by solvothermal method.The morphology,phase structure,up-conversion luminescence and down-conversion luminescence properties of Yb^(3+) and Er^(3+) doping concentration and the energy transfer mechanism were studied.It shows that the doping of Yb^(3+) and Er^(3+) does not cause the phase transition of NaBiF_(4),but influences its morphology.In the NaBiF_(4):Yb^(3+),Er^(3+),Yb^(3+) can transfer energy with Er^(3+),enhancing up-conversion green emission.With Yb^(3+) doping concentration increasing,the up-conversion red-green ratio will increase while the down-conversion intensity of the green emission decreases and that of the red emission increases.Considering the potential application of Na BiF4:x Yb^(3+),y Er^(3+) phosphors in optical illumination,the thermal stability was carried out.