Partitioning behavior and lattice misfit of γ/γ’phases in Ni-based superalloys with different Mo additions

摘要

A low-density single crystal(LDS) alloy with the composition of high Mo content was designed.The extra 1.5 wt% Mo was added in the Alloy A with the composition of Ni-6.5 Al-8.0 Mo-2.4 Cr-6.2 Ta-4.9 Co-1.5 Re-(0.01-0.05) Y(wt%) to study the influence of Mo on the lattice parameter and partitioning behavior.Scanning electron microscope(SEM) with energy-dispersive spectrometer(EDS),transmission electron microscopy(TEM)and high-temperature X-ray diffraction(HT-XRD) were used to observe the microstructure,analyze the elemental content and measure the lattice parameter of the alloys.The natural lattice misfit was calculated by lattice constants which were measured by HT-XRD at the temperature from 25 to 1150℃,and the results showed that the lattice misfit would be more and more negative with temperature increasing.It was found that 1.5 wt% addition of Mo will increase the absolute value of the lattice misfit of γ/γ’phases and the volume fraction of γ’,and at the same time,influence the elemental distribution in γ and γ’ phases,especially Re and Cr.Re has a higher partitioning ratio(k) after the addition of Mo.