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A specific fluorescent chemosensor for copper(Ⅱ) cation recognition

机译:铜(Ⅱ)阳离子识别专用荧光化学传感器

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摘要

The fluorescent spectra of 2, 6-bis(benzimidazol-2-yl) pyridine (compound 2) and its N-substituted compound (1) are studied. The fluorescent characteristics of these compounds and the complexes formed from these compounds with different metal ions have also been investigated. The results show that compound 1 possesses a specific ability to form complex with Cu2+ ions, but compound 2 has not such a property. It is proposed that the specific recognition ability of compound 1 to Cu2+ may attribute to the cyclic configuration of this compound in polar solvent.
机译:研究了2,6-双(苯并咪唑-2-基)吡啶(化合物2)及其N-取代的化合物(1)的荧光光谱。还研究了这些化合物的荧光特性以及由这些化合物与不同金属离子形成的配合物。结果表明,化合物1具有与Cu 2+离子形成络合物的特定能力,但是化合物2不具有这种性质。建议化合物1对Cu2 +的特异性识别能力可能归因于该化合物在极性溶剂中的环状构型。

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  • 来源
    《自然科学进展(英文版)》 |2003年第3期|201-205|共5页
  • 作者

  • 作者单位

    Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100101, China;

    Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100101, China;

    Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100101, China;

  • 收录信息
  • 原文格式 PDF
  • 正文语种 chi
  • 中图分类 化学;
  • 关键词

    2, 6-bis(benzimidazol-2-yl) pyridine, fluorescent sensor, recognition of metal cations;

    机译:2;6-双(苯并咪唑-2-基)吡啶;荧光传感器;识别金属阳离子;
  • 入库时间 2022-08-17 13:31:43
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