SYNTHESIS AND CHARACTERIZATION OF A NOVEL DOPANT (C3-ABSA) FOR SYNTHESIZING TUBULAR POLYANILINE

摘要

4-(3-(4-((4-Nitrophenyl)azo)phenyloxy)propyl)aminobenzene sulfonic acid (C3-ABSA) was synthesized by the reaction of 3-bromide-l-(4-((4-nitrophenyl)azo)phenyloxy)propane (B3) with sodiump-aminobenzene sulfonic acid (ABSA)and acidification with hydrochloric acid. The C3-ABSA was characterized by FTIR, 1H-NMR and second ion mass spectrum (SIMS). The molecular formula of dehydrated C3-ABSA was estimated to be ca. C21H20O6N4S by SIMS. Its decomposition temperature was measured by TGA to be ca. 232°C. It was found that tubular polyaniline (PANI) with a conductivity of 1.1 S/cm at room temperature was successfully synthesized by in-situ doping polymerization in the presence of C3-ABSA as a dopant.