程序升温表面反应技术在固体催化剂上的应用(上)

摘要

The basic principles,equipments and experimental conditions of temperature programmed surface reaction(TPSR) technique were introduced.The applications of the TPSR technique in the research for catalysts in petrochemical industry in recent ten years were summarized in detail,which included the reforming oxidation of olefins and alkyls,Fischer-Tropsch synthesis,catalytic reduction of NOx,oxidation reduction of alcohol and aldehyde,oxidation of CO,and decomposition of compounds containing nitrogen,sulfur and chlorine.The development of TPSR in future was discussed.%简要介绍了程序升温表面反应(TPSR)技术的基本原理、TPSR的装置及实验条件的选择,重点综述了近十年来TPSR技术在烯烃和烷烃的重整氧化、费托合成、NUx的催化还原、醇醛的氧化还原、CO的氧化、硫氮氯化合物的分解等催化研究中的应用情况,并探讨了TPSR技术的发展趋势.