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The synergic extraction of uranium (Ⅵ) with tri-n-butyl phosphate (TBP) and petroleum sulfoxides(PSO)/benzene

机译:磷酸三正丁酯(TBP)和石油亚砜(PSO)/苯协同萃取铀(Ⅵ)

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摘要

The synergistic extraction of uranium (Ⅵ) from nitric acid aqueous solution with a mixture of tri-n-butyl phosphate (TBP) and petroleum sulfoxides(PSO) in benzene was studied. It has been found that the maximum synergistic extraction effect occurs where the molar ratio of PSO to TBP is one to two. The composition of the complex of synergistic extraction is UO2(NO3)2.TB P.PSO. The formation constant of the complex KTp=57.44.
机译:研究了磷酸三正丁酯(TBP)和石油亚砜(PSO)在苯中从硝酸水溶液中协同萃取铀(Ⅵ)。已经发现,当PSO与TBP的摩尔比为1∶2时,产生最大的协同萃取作用。协同萃取复合物的组成为UO2(NO3)2.TB P.PSO。配合物KTp的形成常数= 57.44。

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