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Carbon-Supported Silver Catalysts for CO Selective Oxidation in Excess Hydrogen

机译:碳负载下过量氢气中CO选择性氧化的银催化剂

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摘要

碳材料被用作对用常规湿浸渍法,和他们的催化性质被准备的 47 号元素银的化学符号催化剂的支持因为在在在 483 K 下面的温度的过量氢的公司选择氧化被测试。例如 N2 吸附, XPS, TPD,紫外力的医生, TEM 和 SEM,许多技术被用来决定影响物理并且 47 号元素银的化学符号的性质上的碳的化学性质催化剂。碳表面上的缺点为银离子用作成核地点,这被发现,当碳表面上的官能团导致了他们的减小到金属性的形式时。碳上的银粒子的形成被管理由同类或异相成核在受精和随后的激活过程期间。最好的催化表演与银 nanoparticles (大约 12 nm ) 的一致大小分布与 Ag/carbon 黑催化剂被获得,中等 BET (与一我酣睡的结构) ,并且碳氧组的有限数量。研究显示碳材料是对为在过量氢的公司的优先的氧化的银催化剂的潜在地好的支持。给词调音:碳支持;催化性质;背叛;
机译:Carbon materials were used as supports for Ag catalysts that are prepared using the conventional wet impregnation method, and their catalytic properties for CO selective oxidation in excess hydrogen at temperatures below 483 K were tested. A variety of techniques, e.g. N2 adsorption, XPS, TPD, UV-Vis DRS, TEM and SEM, were used to determine the influence of physical and chemical properties of the carbon on the properties of Ag catalyst. It was found that defects on the carbon surface served as nucleation sites for silver ions, while functional groups on carbon surface induced their reduction to the metallic form. The formation of silver particles on carbon was governed by homogeneous and/or heterogeneous nucleation during the impregnation and subsequent activation processes. The best catalytic performance was obtained with a Ag/carbon black catalyst with a uniform size distribution of silver nanoparticles (about 12 nm), moderate BET surface area (with a mesoporous structure), and a limited amount of carbon-oxygen groups. The research indicates that carbon materials are potentially good supports for silver catalysts for preferential oxidation of CO in excess hydrogen.

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