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Preparation and Characterization of Nanotitanium Dioxide Coating Film Doped with Fe3+ Ions on Porous Ceramic

机译:多孔陶瓷上掺杂Fe3 +离子的纳米二氧化钛涂层膜的制备与表征

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摘要

The nanotitanium dioxide (TiO2) photocatalytic and porous ceramic filtering technique is one of the advanced methods to effectively treat organic wastewater. The TiO2 sol doped with Fe3+ ions was prepared by sol-gel processing. The influences of the process conditions of coating nanophotocatalytic material-Fe3+-TiO2 film on the surface of porous ceramic filter by dipping-lift method on the performance of porous ceramic filter were studied. The porous ceramic filters have two functions at the same time,filtration and photocatalytic degradation. The results of this study showed that the pH and viscosity of the sol,amount of Fe3+ ions doped as well as the coating times greatly affect the quality of coating film,the performance parameters and the photocatalytic activity of the porous ceramic filter. When the pH of the sol is 3-4,the viscosity is about 6 mPa·S,the amount of doped Fe3+ ions is about 2.0 g/L,the porous ceramic filter has been shown to have the best filtering performance and photocatalytic activity. In this condition,the porosity of porous ceramic is about 42.5%,the pore diameter is 8-10μm. The degradation of methyl-orange is 74.76% under lighting for 120 min.
机译:纳米二氧化钛(TiO2)光催化和多孔陶瓷过滤技术是有效处理有机废水的先进方法之一。通过溶胶-凝胶法制备了掺杂Fe3 +离子的TiO2溶胶。研究了浸提法在多孔陶瓷滤池表面涂纳米光催化材料-Fe3 + -TiO2膜的工艺条件对多孔陶瓷滤池性能的影响。多孔陶瓷过滤器同时具有过滤和光催化降解两种功能。研究结果表明,溶胶的pH值和粘度,Fe3 +离子的掺杂量以及涂覆时间对涂膜质量,性能参数和多孔陶瓷滤池的光催化活性都有很大影响。当溶胶的pH值为3-4时,粘度约为6 mPa·S,Fe3 +离子的掺杂量约为2.0 g / L,多孔陶瓷滤池具有最佳的过滤性能和光催化活性。在这种条件下,多孔陶瓷的孔隙率约为42.5%,孔径为8-10μm。光照120分钟,甲基橙的降解率为74.76%。

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