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《武汉理工大学学报:材料科学英文版》
>Effect of Nucleating Agents and Heat Treatments on the Crystallization of Magnesium Aluminosilicate Transparent Glass-ceramics
Effect of Nucleating Agents and Heat Treatments on the Crystallization of Magnesium Aluminosilicate Transparent Glass-ceramics
The crystallization behavior and transparent property of MgO-Al2O3-SiO2 (MAS) glasses with TiO2 and TiO2+ZrO2 as nucleating agents were discussed by differential thermal analysis, X-ray diffraction, field emission-environment scanning electron microscope, energy dispersive spectrum and UV-VIS-NIR scanning spectrophotometer. It was found that the glass crystallized at 950 ℃ with ZrO2 less than 3% could obtain transparent glass ceramic, which presented purple to colorless. With the nucleating agent additives (5% TiO2+3% ZrO2), the colorless transparent glass-ceramics with spinel as the main crystal phase could be prepared, and the transmittance reached about 80% . As the crystallized temperature increase to 1 000 ℃, besides spinel(MgAl2O4), sapphirine (Mg3.5Al9Si1.5O20) and ZrTiO4 precipitated from matrix glass, and the transmitance of glass-ceramic decreased.
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