The resources of fossil fuel will be dried up in the near future. Moreover,greenhouse gas from fossil fuel burning has worsened the global warming situation. The development of sustainable en-ergy has currently become a hot issue in the world. H2 as cleanest ernergy was combused with O2 to pro-duce pure water. The paper presents a model of bio-hydrogenation process with anaerobic bacterial growth on organic wastewater. Data from laboratory scale reactors operating with artificial substrates u-sing bacteria from agricultural waste were conducted. The calculating bio-hydrogen yields and assuming from the waste stream were suitable properties in the digestion. Bacteria played a very important role in the processes of bio-hydrogenation. Bacteria that produce hydrogen were isolated by its characteristic of heat-resistance. Factors that affect the efficiency of bio-hydrogenation process include pH, temperature and the ratio of biomass to substrate concentration( F/M) . By using glucose as the substrate with Clos-tridium sp. seeding,it is shown that of bio-hydrogenation can be produced efficiently in the experiment. Methanogenesis which consumes H2 may be prevented by special operation,and optimum parameters, such as pH around 5,Temperature at 35 ℃,HRT approximately 8hours and F/M between 25% ~50%. And the maximum hydrogen concentration is found to be 88. 6%( V/V) for practical application were obtained from the model.%化石燃料的枯竭,化石燃料燃烧排放的温室气体加剧了全球变暖的问题,已经成为世界的热点问题之一.氢气作为清洁能源,与沼气和化石燃料相比,燃烧产物只有水.利用有机废弃物厌氧发酵制氢气,通过厌氧反应器和农业废弃物生物制氢模型,计算实验过程中生物产氢量和废弃物消解与微生物生长的关系.实验过程表明:在生物制氢过程中,产氢细菌作用显著,产氢菌可以通过其耐热性进行筛选.而影响生物制氢效率的因素还包括:pH值、温度和有机负荷率等.通过有机物梭菌转化培养,生物制氢纯度高且过程可以有效地进行.采用产甲烷菌抑制步可以消除其H2 的消耗.当pH值为4. 5~5,温度为35 ℃,水力停留时间( HRT)为8 h,有机负荷率为25 % ~50 %时,通过模型对实验数据拟合得到最大氢气体积分数为88. 6 %.
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