Fe (III) 2,9,16,23 tertracarboxy phthalocyanine (Fe (III) taPc) was synthesized, and bonded to polystyrene (PS) with covalence by Friedel Crafts reaction to form a new polymer (Fe (III) taPc PS) (polymer (II)). UV VIS and Infrared spectra indicated that Fe (III) taPc was successfully bonded to PS. A photoreceptor device of sandwich structure consisting of alternate layers of polymer (II) and fullerene (C 60 ) was prepared. The experiment results show that the photoconductivity of the photoreceptor is higher than that of the single layer film of polymer (II) or C 60 , because of the charge transfer effect between the layers.
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