Structural model for the first wall W-based material in ITER project

摘要

The preparation, characterization, and test of the first wall materials designed to be used in the fusion reactor have remained challenging problems in the material science. This work uses the first-principles method as implemented in the CASTEP package to study the influences of the doped titanium carbide on the structural stability of the W–Ti C material. The calculated total energy and enthalpy have been used as criteria to judge the structural models built with consideration of symmetry.Our simulation indicates that the doped Ti C tends to form its own domain up to the investigated nano-scale, which implies a possible phase separation. This result reveals the intrinsic reason for the composite nature of the W–Ti C material and provides an explanation for the experimentally observed phase separation at the nano-scale. Our approach also sheds a light on explaining the enhancing effects of doped components on the durability, reliability,corrosion resistance, etc., in many special steels.