The influence of mechanical activation on the leaching behaviour of scheelite was studied bymeans of fine grinding in an attritor and subsequently HCl leaching in presence of PO43-.Results showed that after fine grinding in the attritor,the reaction rate of scheelitewith HCl-Na3PO4 solution was remarkably increased,the extraction of W increased fromabout 8 to 99%.The IR spectra and X-ray diffraction analysis indicated that in addition toan enlargement of surface area the fine grinding action had made also changes of fine struc-ture and reactivity of solid surface,hence the leaching process of scheelite can be carried outunder mild leaching conditions.
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