含铋复合氧化物可见光催化材料研究进展

摘要

Photocatalysts could utilize solar energy to remedy environmental pollutions thus attract world wide attention. Some bismuth-containing complex oxides could be activated by visible light and mineralize organic pollutants. In this paper we reviewed recent progresses on the development of Bi2WO6, BiVO4 and Bi2MoO6 photocatalysts. By controlling the particle size, morphology, crystaUinity and other microstructures via different methods, the photocata-lytic activities in the degradation of organic dyes, colorless model pollutants such as phenol and acetaldehyde, and disinfection of these visible light induced photocatalysts were greatly enhanced. Through further development, bismuth-containing complex oxides are hopeful to be applied in the field of environmental remediation.%光催化材料因可以利用太阳能净化环境,受到广泛关注.一些含铋复合氧化物半导体可直接被可见光激发,更有效地利用太阳能,实现有机污染物的矿化,成为近期光催化材料研究领域的热点之一.本文概述了Bi2WO6、BiVO4和Bi2MoO6三种常见的含铋复合氧化物可见光催化材料体系的近期研究进展.通过合成方法的优选、晶粒成核和生长的调节,实现晶粒尺寸、形貌、结晶度等微结构的控制,从而获得小尺寸、高表面积的光催化材料,无论是在有机染料、苯酚和乙醛等多种模拟污染物的矿化,还是抗菌等方面,它们皆呈现出优秀的可见光催化性能.通过进一步发展,含铋复合氧化物有望实现在环境净化领域的应用.