首页> 中文期刊> 《东华大学学报:英文版》 >THE POLYELECTROLYTIC BEHAVIOURS OF ACIDIC AQUEOUS SOLUTIONS OF CHITOSAN IN THE PRESENCE OF EXTERNAL SALTS

THE POLYELECTROLYTIC BEHAVIOURS OF ACIDIC AQUEOUS SOLUTIONS OF CHITOSAN IN THE PRESENCE OF EXTERNAL SALTS

         

摘要

The viscosities of chitosan-HAC in aqueous solution with various amount of NaAC have beenmeasured.Based on the analysis of experimental data,an empirical equation is deduced to des-cribe the relationship between the intrinsic viscosity and the concentration of external salt in thechitosan solution:[η]=[η]∞+P/mnand another empirical equation is proposed for describing the variation of reduced viscosity ofchitosan solution as function of salt and chitosan concentrations:(ηsp/c)salt={D+A/(1+BC+HC2)}·{1-1/(([η]m=0)/([η]m=0-[η]∞)+P/mR)+(C/m)}where the first term represents the relationship between viscosity and polymer concentration in theabsence of external salt,while the second term represents the correction value on viscosity in thepresence of external salt.

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