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Analysis of irrationality of coal susceptibility to spontaneous combustion determination method with fluid oxygen adsorption

机译:流体氧吸附自燃法测定煤敏感性的不合理性分析。

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摘要

Based on experiment results and theoretical analysis,pointed out that the method of coal susceptibility to spontaneous combustion determination with fluid oxygen adsorption can not present the essence of coal oxidation process and oxidation reaction.The method is incorrect,paying attention at one aspect and ignoring the rest.The method is not reasonable for coal susceptibility to spontaneous combustion determination.Susceptibility to spontaneous combustion of coal reflects chemical property of coal oxidation with oxygen absorption and heat release at low temperature.Coal's susceptibility to spontaneous combustion is mainly decided by the number of molecules with reaction activation energy and activation molecule production rate at certain temperature.Therefore,index of susceptibility to spontaneous combustion should adopt accumulative value or trend of heat release or oxygen adsorption during oxidation process.
机译:根据实验结果和理论分析,指出利用液体氧吸附自燃测定煤的敏感性方法不能代表煤氧化过程和氧化反应的实质。该方法是不正确的,一方面要注意,却忽略了该方法对煤的自燃敏感性测定是不合理的,煤的自燃敏感性反映了煤在低温下具有氧吸收和放热的氧化性质,而煤对自燃的敏感性主要取决于分子数因此,对自燃的敏感性指标应采用氧化过程中热量释放或氧气吸附的累积值或趋势。

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