Modeling the kinetics of methane conversion in steam reforming process of coke-oven gas based on experimental data

摘要

Steam-reforming is an effective approach for upgrading methane and hydrocarbon of coke-oven gas into CO and H2, but the kinetic behavior needs more study. We investigated the conversion of methane in coke-oven gas by steam reforming process in an electric tubular flow at 14 kPa with temperature varying from 500℃ to 950℃, and developed a kenetic model for , ignoring the effects of adsorption and diffusion. The optimal dynamic conditions for methane conversion 14 kPa are as follows: the ratio of the amount of water to the amount of methane is from 1.1 to 1.3; the reaction temperature is from 1 223 K to 1 273 K. The methane conversion rate is larger than 95% when the ratio of the amount of water to the amount of methane is 1.2 at a temperature above 1 223 K with the residence time up to 0.75 s.