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Effect of BaO addition on relative density and electric conductivity of xNi/10NiO-NiFe_2O_4 cermets

机译:添加BaO对xNi / 10NiO-NiFe_2O_4金属陶瓷相对密度和电导率的影响

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摘要

xNi/10NiO-NiFe_2O_4 (x=5, 10, 17) cermets and those doped with 1% BaO (mass fraction) were prepared by cold isostatic pressing at 200 MPa and sintering in nitrogen atmosphere at 1 473 K. The effects of BaO addition on relative density, microstructure and electric conductivity of cermets were investigated. The results show that relative densities of xNi/10NiO-NiFe_2O_4 cermets (x-=5, 10, 17) doped with 1% BaO at 1 473 K in nitrogen atmosphere are increased by 0.49%, 1.45% and 2.99% compared with those of the undoped BaO cermets, respectively. Moreover, the electric conductivities (21.98, 28.37 and 50.10 S/cm) of xNi/10NiO-NiFe_2O_4 cermets (x=5, 10, 17) doped with 1% BaO at 1 233 K are improved compared with those (18.70, 22.79 and 39.58 S/cm) of xNi/10NiO-NiFe_2O_4 cermets (x=5, 10, 17), respectively. This indicates that perhaps the addition of BaO or formation of BaFe_2O_4 and Ba_2Fe_2O_5 has an active effect on electric conductivities ofxNi/10NiO-NiFe_2O_4 (x=5, 10, 17) cermets.
机译:通过在200 MPa下冷等静压并在氮气气氛中以1 473 K烧结制备xNi / 10NiO-NiFe_2O_4(x = 5、10、17)金属陶瓷和掺有1%BaO(质量分数)的金属陶瓷。BaO的影响研究了金属陶瓷的相对密度,微观结构和电导率。结果表明,在氮气氛下,以1473 K掺杂1%BaO的xNi / 10NiO-NiFe_2O_4金属陶瓷(x- = 5,10,17)的相对密度分别比其高0.49%,1.45%和2.99%。未掺杂的BaO金属陶瓷。此外,在1233 K下掺杂了1%BaO的xNi / 10NiO-NiFe_2O_4金属陶瓷(x = 5,10,17)的电导率(21.98、28.37和50.10 S / cm)与(18.70、22.79和分别为xNi / 10NiO-NiFe_2O_4金属陶瓷(x = 5、10、17)39.58 S / cm)。这表明也许添加BaO或形成BaFe_2O_4和Ba_2Fe_2O_5对xNi / 10NiO-NiFe_2O_4(x = 5、10、17)金属陶瓷的电导率具有积极影响。

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