Lignite,generally containing high levels of side chains and oxyfunctional groups,cannot lead to the formation of ordered coke texture. Changes in the properties of the lack of plasticity and fluidity during carbonization using a mixture of carbon monoxide and water conversion process were studied by the microscope photometry,by plotting Rmnx values against Rm,Rmin and bireflectance, as well as quantitative estimation of the optical anisotropy, based on 500 pointcounts. The classification of the carbon forms of this converted lignite is proposed as follows: Isotropic ,Mosaic ,Fibrous ,Flow & Leaf,Mesophase-sphere ,Fusitic ,Inertic ,Pore & fissure. This microtextures of coke were also analysed by using X-ray diffraction. It reveals that the values of diffractional angle,interlayer spacing (002) and the height of the crystallite are in good relationship with the degree of polymerization from the original lignite to its water gas shift reaction products.
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