Polyaniline and N-instead of polyaniline of electrochromic material are usually two preparation methods:chemical polymerization and electrochemical polymerization process. The structure and properties of the polymer were closely related to its preparation process and preparation method, the advantages and disadvantages of different polymerization methods and the conditions of affecting the polymer film formation were also listed. Compared the properties of the two kinds of polymers, such as the electrochromic properties, electrical conductivity and solubility, the causes of their different characteristics and the problems of improving these properties were analyzed, which provided a theoretical reference for the study of organic electrochromic material.%电致变色材料聚苯胺和N-取代聚苯胺通常有两种制备方法:化学聚合法和电化学聚合法,聚合物的结构和性质与其制备过程和制备方法密切相关,本论文列举了不同聚合方法的优缺点以及影响聚合成膜的条件。通过对聚苯胺和N-取代聚苯胺这两类聚合物的电致变色特性、电导率和溶解度的比较,分析了它们不同特性的产生原因以及改善这些性质所存在的问题,为有机电致变色材料的研究提供理论参考。
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