首页> 中文期刊>大地构造与成矿学 >安徽宁国兰花岭钨钼矿床含矿岩体的地球化学特征、LA-ICP-MS锆石U-Pb年代学研究

安徽宁国兰花岭钨钼矿床含矿岩体的地球化学特征、LA-ICP-MS锆石U-Pb年代学研究

     

摘要

The Lanhualing tungsten-molybdenum deposit is a skarn-type deposit located in Ningguo county, Anhui province. This deposit is mainly hosted in the Yinzhubu Formation and the Yanwashan Formation of Ordovician, and genetically related to the Lanhualing granite. The Lanhualing granite belongs to high-K calc-alkaline series with high alkali (Na2O+K2O=4.00%–7.03%), SiO2 (67.87%–74.92%) and MgO (0.62%–1.23%) contents. The granitic rocks show right-dipping chondrite normalized REE patterns with weakδEu anomalies. The granitic rocks are relatively enriched in large ion lithophile elements (LILE) and depleted in high field strength elements (HFSE). The ore-bearing granite was dated at 148.17±0.94 Ma by LA-ICP-MS zircon U-Pb method. The late Yanshanian is the main tungsten mineralization epoch in the South Anhui-north Jiangxi area;and indeed, the Dongyuan, Zhuxi, Yangchuling, Dahutang and other large and super-large tungsten deposits were formed in this period. Geochemical Characteristics of the Lanhualing granite indicate a crustal source but with mantle input under tectonic regime of compression thickening.%兰花岭钨钼矿床为皖南山区一矽卡岩型矿床,赋矿层位主要为奥陶系印诸埠组和砚瓦山组。与成矿相关的兰花岭岩体属花岗岩,为高钾钙碱性系列岩石, SiO2含量高, Al2O3中等, MgO较高。全碱(Na2O+K2O)含量在4.00%~7.03%之间,里特曼指数为0.51~1.92, A/NCK 比值均大于1, Nb、Ta 亏损, Mg#值小。稀土元素呈轻稀土富集的右倾配分模型, LREE/HREE比值和(La/Yb)N均较大,δEu异常不明显,δCe负异常较弱。微量元素地球化学研究表明大离子亲石元素(LILE)富集,高场强元素(HFSE)总体亏损。通过LA-ICP-MS锆石U-Pb法确定地表含矿岩体的年龄为148.17±0.94 Ma,属燕山期晚侏罗世。这一时期也是皖南–赣北一系列大型超大型钨矿的主要成矿期,如东源、朱溪、阳储岭、大湖塘等。岩体成因以壳源重熔为主,侵位过程中有幔源岩浆混入。兰花岭岩体为陆内挤压加厚背景下岩浆活动的产物,与旌德岩体属同期次岩浆活动的产物,结合物探资料显示兰花岭岩体在深部可能与旌德岩体相连。

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