电化学基础（Ⅴ）--电极过程动力学及电荷传递过程

摘要

电荷传递过程是电化学反应的本质。了解电荷传递过程有助于揭示电化学反应的内在规律，实现电化学工业过程控制和电化学反应设计。本文通过回顾电极过程动力学理论的发展历程及数学表达式的演化过程，阐述电化学反应中电荷传递过程的科学背景，理解其中的科学思想，相信对于促进现代电化学研究的发展具有启示意义。%　　The charge-transfer process is the basis of an electrochemical reaction. The knowledge about charge-transfer processes can help us to recognize to the inherent nature through the electrochemical reaction representation, and to achieve the control in the electrochemical industry and the electrochemical reaction design. In this paper, we reviewed the scientific background of electrochemical kinetic and development of the charge-transfer process, and rethought about their scientific idea. We believe that a historical review can be very helpful for our future research.