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A Study of Degradation in Vegetable Oils by Exposure to Sunlight Using Fourier Transform Infrared Spectroscopy

机译:傅里叶变换红外光谱法研究日光照射下植物油的降解

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There are a diversity and variability of oil producing plants and different extraction methods. These vegetable and essential oils are substances stored and released by plants from their fruits, leaves, flowers, bark and stem, being complete of plant origin that provides some benefits. In the plant these oils are also known as antioxidant substances, which have the function of natural protection. It is known that the extraction method has a strong influence on its quality and composition due to its variability and environmental conditions, besides possible adulteration. Oils that are rich in polyunsaturated fatty acids are the most relevant to the cosmetic industry but are most sensitive to oxidation. The oxidation of these oils generates what is known as rancidity, with the presence of smaller and undesirable molecules, thus reducing the quality of the oil beyond its nutritional value, making them harmful to human health. Stocking conditions, such as exposure to sunlight and heat, are major phenomena that accelerate the degradation of these oils. Infrared spectrometry with Fourier transform (FTIR) is a tool with potential to evaluate the degradation effect of vegetable oils. Infrared spectra of Almond (Prunus dulcis), Andiroba (Carapa guianensis aubl.), Copaíba (Copaifera langsdorffi) and Rosehip (Rosa aff. Rubiginosa) oils before and after exposure to sun light for 90 days were analyzed, with objective of evaluating the effect of the degradation on the composition of the oil, which were acquired in local commerce of the city Porto Velho. The spectra trends show the occurrence of oxidation, with the reduction of unsaturation, in addition to the fractionation of carbon chains and appearance of functional groups such as aldehyde and alcohol.
机译:油生产植物的多样性和变异性和不同的提取方法。这些蔬菜和精油是由植物,叶子,花朵,树皮和茎的植物储存和释放的物质,这些植物是提供一些益处的植物来源。在植物中,这些油也称为抗氧化物质,具有自然保护的功能。众所周知,除了可能的掺杂外,提取方法对其质量和组成具有很大的影响。富含多不饱和脂肪酸的油是与化妆品行业最相关的油,但对氧化最敏感。这些油的氧化产生了所谓的腐蚀性,存在较小和不希望的分子,从而将油的质量降低到超出其营养价值的质量,使其对人体健康有害。袜子条件,如暴露在阳光和热量,是加速这些油的降解的主要现象。具有傅里叶变换(FTIR)的红外光谱法是一种有可能评估植物油的降解效果的工具。杏仁(Prunus dulcis),Andiroba(Carapa Guianensis Amubl。),Copaíba(Copaifera Langsdorffi)和玫瑰果(Rosa Aff。在暴露于Sun灯之前和之后的玫瑰果(Ruosafosa)的玫瑰花,评价效果石油组成的降解,在港口城市港口的港口中获得。光谱趋势表明,除了碳链的分馏和醛和醇等官能团的外观之外,不饱和的氧化趋势均显示出氧化的发生。

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