Near Resonant Electronic and Rotational Energy Transfer AB（^1∏, J）＋C（^slj）→AB（^1∏, J＇）＋C（^sl j＇）

摘要

In our previous theoretical study, the theoretical model of the collision-induced electronic and rotational energy transfer of AB(1∑, J) + C(slj) → AB(1∑, J') + C(slj') was presented. To further study the collision-induced electronic and rotational energy transfer theoretically on AB(1∏,J)+C(slj)→AB(1∏,J1)+C(slj') a theoretical model is presented, based on the time-dependent first-order Born approximation, taking into account the anisotropic LennardJones interaction potential and 'straight-line' trajectory approximation. The changing tendency of the transitional probabilities with the anisotropic parameter is discussed.