首页> 中文期刊> 《化工学报》 >环渤海湾海滨土稠油污染特征调查

环渤海湾海滨土稠油污染特征调查

         

摘要

There have been 29 producing oilfields in the Bohai Bay rim, belonging to three domestic main oil oilfields companies (Liaohe, Dagang, Shengli). The procedure of production is running the risk of crude oil dripping, dropping, leaking, et al. The leaking crude oil caused severe oil contamination in the coastal territory. It is necessary to conduct a thorough renovation. While the sonochemistry has an unique advantage in the realization of separating oil-soil hybrid system, it is considered as one of the most potential technologies to carry out oil-soil homogeneous system decontamination. In this regard, we perform our investigations on local oilsands systems (MOS) to determine physical characteristics of system, the calcium, magnesium, bicarbonate ion concentrations, ultra-fine silica distribution and oil content distribution in contaminated soil. These are the main factors influencing recovery efficiency and purification extent. The results obtained show that the soil of Yellow River estuary region which is contaminated by petroleum is alluvial fine soil, viscosity of detained oil is substantially affected by the temperature with the features of non-Newtonian fluid and a higher pour point, the iron content of soil sample is adequately high, the maximum content of calcium and magnesium cations is 353.3 mg · kg-1 and 690 mg · kg-1 respectively, bicarbonate ion content close to 180 mg · kg-1. According to its specific size and mineralogical properties, the seaside soil can be considered as one of active solids, which can affect the later oil-soil separation. Furthermore, the rich distribution of soil contaminated by oil is close to the surface, especially in 30 cm depth range or so.%引言rn中国三大油田(辽河、大港、胜利)的石油储量达数十亿吨[1],仅渤海湾就有油田29个[2].rn海滨土是在静水或缓慢的流水环境中沉积,经物理化学和生物化学作用形成的,属现代新近沉积物[3].东营渤海之滨的黄河口,从地质学上讲,土层属于细粒海相沉积土[4-5].该沉积土由暴露于地表的各类岩石经物理风化破碎,再经机械搬运、磨蚀、分选、堆积而成,比表面积大,颗粒表面带负电荷,粒间连接强[6-7].

著录项

  • 来源
    《化工学报》 |2011年第1期|237-242|共6页
  • 作者单位

    中国海洋大学环境科学与工程学院海洋环境与生态教育部重点实验室,山东,青岛,266100;

    中国海洋大学环境科学与工程学院海洋环境与生态教育部重点实验室,山东,青岛,266100;

    中国海洋大学环境科学与工程学院海洋环境与生态教育部重点实验室,山东,青岛,266100;

    浙江大学材料与化工学院教育部膜材料与水处理工程中心,浙江,杭州,310027;

    中国海洋大学环境科学与工程学院海洋环境与生态教育部重点实验室,山东,青岛,266100;

  • 原文格式 PDF
  • 正文语种 chi
  • 中图分类 X531;
  • 关键词

    稠油; 细粒土; 污染调查;

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