INVESTIGATION ON SYNTHESIS, STRUCTURE AND PROPERTIES OF THE CLUSTER COMPLEX,（MoS4）Fe（MoS4O） （C4H9）4N3

摘要

＜正＞ In this paper, we report a new Mo-Fe-S cluster complex containing an oxygen ligand. Itwas synthesized by the reaction of （NH4）2 MoS4, FeCl3 in the solution of sodium glycol. The chemical formula of the crystal, [（MoS4） Fe （MoS4O）] [（C4H9）4N]3, was characterized byX-ray. This complex was determined by IR, UV/Vis and Mossbauer spectra as well. The re-suits from Mossbauer spectra of the complex show an isomer shift, δm = 0.2263mm/s and aquadrupole splitting, Eq = 0.4527mm/s. The complex has some activity for the reduetion of aectylene to ethylene in the presenceof KBH4.