A new phase of(2×2)has been observed as a result of hydrogen ion sputter etching on a clean reconstructed Si(100)-(2×1)surface using low energy electron diffraction(LEED).It has been found that the(2×1)surface first transformed into a metastable c(4×4)phase following hydrogen ion etching and after further anneal of the sample,a(2×2)phase can be obtained.Intensity vs electron energy(I-V)curves for the Si(100)-(2×2)pattern have been measured using a special video LEED system.
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