机译：Using low-energy electron diffraction(LEED)and scanning tunnelling microscopy (STM) it has been found that glycine molecules adsorbed on Cu(001) can form but only the (2×4） superstructures.On the basis of the missing LEED spots of the surface,it has been concluded that.each(2×4) unit cell consists of two molecules,one being the mirror image of the other,the C-C axis of both molecules lies in the mirror plane of the Cu substrate without a significant shift and twish from the plane;and the two O atoms of the carboxylate group of both molecules locate at the same height level without significant buckling.According to these conclusions,a structural model has been propsed for the (2×4） superstructure (a model for the c(2×4） supersturcture already exists).We argue that the (2×4) and c(2×4) superstructures must have similar specific surface free energy,that their hydrogen bonds must be of N-H-OII type,and that their local adsorption geometry must be similar or even the same.The advantage of combining STM with LEED to determine surface sturctures is clearly demonstrated.
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