Growth and photoluminescence properties of inclined ZnO and ZnCoO thin films on SrTiO3(110) substrates

摘要

ZnO thin film growth prefers different orientations on the etched and unetched SrTiO3(STO)(ll0)substrates.Inclined ZnO and cobalt-doped ZnO(ZnCoO)thin films are grown on unetched STO(ll0)substrates using oxygen plasma assisted molecular beam epitaxy,with the c-axis 42° inclined from the normal STO(ll0)surface.The growth geometries are ZnCoO[100]//STO[1（1）0] and ZnCoO[1（1）1]//STO[001].The low temperature photoluminescence spectra of the inclined ZnO and ZnCoO films are dominated by D0X emissions associated with A0X emissions,and the characteristic emissions for the 2E(2G)-→4A2(4F)transition of Co2+ dopants and the relevant phonon-participated emissions are observed in the ZnCoO film,indicating the incorporation of Co2+ ions at the lattice positions of the Zn2+ ions.The c-axis inclined ZnCoO film shows ferromagnetic properties at room temperature.